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Liquefied gases are in common use for a variety of purposes For example, liquid propane in cylinders serves as a domestic fuel, liquid oxygen is carried in rockets, natural gas is liquefied for ocean transport, and liquid nitrogen is used for low-temperature refrigeration In addition, gas mixtures (eg, air) are liquefied for separation into their component species by fractionation Liquefaction results when a gas is cooled to a temperature in the two-phase region This may be accomplished in several ways: 1 By heat exchange at constant pressure 2 By an expansion process from which work is obtained 3 By a throttling process The first method requires a heat sink at a temperature lower than that to which the gas is cooled, and is most commonly used to precool a gas prior to its liquefaction by the other two methods An external refrigerator is required for a gas temperature below that of the surroundings The three methods are illustrated in Fig 95 The constant-pressure process (1) approaches the two-phase region (and liquefaction) most closely for a given drop in temperature The throttling process (3) does not result in liquefaction unless the initial state is at a high enough pressure and low enough temperature for the constant-enthalpy process to cut into the two-phase region This does not occur when the initial state is at A If the initial state is at A', where the temperature is the same but the pressure is higher than at A, then isenthalpic

6:

.

Let s peer into the /etc/rcd/rc3d directory and see what s there:

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Figure 18-13. The variable Pressed will hold True or False. If the Enter button is pressed and released during the first 3 seconds, the NXT BUTTONS SENSOR block will detect the press and release and change the logic value to True. A value of True or False will continue to be written to the Pressed variable block until the 3 seconds expire. When the program starts, the initial value will be False, but it can change anytime to True if the Enter button is bumped. When the WAIT block ends (after 3 seconds), we need to display Pressed or Not Pressed on the LCD screen. To do this, we ll drop in another VARIABLE block. This time I m going to choose my Pressed variable again, but I m changing its Action section option to Read (see Figure 18-14).

expansion by process (3') does result in the formation of liquid The change of state from A to A' is most easily accomplished by compression of the gas to the final pressure at B, followed by constant-pressure cooling to A' Liquefaction by isentropic expansion along process (2) may be accomplished from lower pressures (for given temperature) than by throttling For example, continuation of process (2) from initial state A ultimately results in liquefaction The throttling process (3) is the one commonly employed in small-scale commercial liquefaction plants The temperature of the gas must of course decrease during expansion This is indeed what happens with most gases at usual conditions of temperature and pressure The exceptions are hydrogen and helium, which increase in temperature upon throttling unless the initial temperature is below about 100 K for hydrogen and 20 K for helium Liquefaction of these gases by throttling requires initial reduction of the temperature to lower values by method 1 or 2 As already mentioned, the temperature must be low enough and the pressure high enough prior to throttling that the constant-enthalpy path cuts into the two-phase region For example, reference to a TS diagram for air6 shows that at a pressure of 100 atm the temperature must be less than 169 K for any liquefaction to occur along a path of constant enthalpy In other words, if air is compressed to 100 atm and cooled to below 169 K, it can be partly liquefied by throttling The most economical way to cool a gas for liquefaction is by countercurrent heat exchange with the portion of the gas that does not liquefy in the throttling process The Linde liquefaction process, which depends solely on throttling expansion, is shown in Fig 96 After compression, the gas is precooled to ambient temperature It may be even further cooled by refrigeration The lower the temperature of the gas entering the throttle valve, the greater the fraction of gas that is liquefied For example, a refrigerant evaporating in the cooler at 23315 K (-40 C) provides a lower temperature at the valve than if water at 29415 K (21 C) is the cooling medium A more efficient liquefaction process would replace the throttle valve by an expander, but operating such a device into the two-phase region is impractical However, the Claude process, shown in Fig 97, is based in part on this idea Gas at an intermediate temperature.

[root@fedora-serverA ~]# ls -l /etc/rcd/rc3d/ total 232 lrwxrwxrwx 1 root root 22 2008-11-05 01:34 S97yum-updatesd -> /initd/yum-updatesd lrwxrwxrwx 1 root root 24 2008-11-05 01:42 K02NetworkManager -> /initd/NetworkManager lrwxrwxrwx 1 root root 34 2008-11-05 01:42 K02NetworkManagerDispatcher -> /initd/ NetworkManagerDispatcher lrwxrwxrwx 1 root root 19 2008-11-05 01:10 K05saslauthd -> /initd/saslauthd lrwxrwxrwx 1 root root 16 2008-11-05 01:22 K10psacct -> /initd/psacct lrwxrwxrwx 1 root root 14 2008-11-05 01:36 S55sshd -> /initd/sshd <OUTPUT TRUNCATED>

Perry and D Green, op cif,Fig 2-5, p 2-213

From the preceding sample output, you will see that K05saslauthd is one of the many files in the /etc/rcd/rc3d directory (Line 5) Thus, when the file K05saslauthd is executed or invoked, the command actually being executed instead is

7 - - - - - - - - - - -

By the same token, if S55sshd is invoked, the following command is what really gets run:

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