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cationic polymerization yields only very-low MW products because of extensive chaintransfer reactions [Kubisa, 1996; Lapienis and Penczek, 1984; Penczek and Libiszowski, 1988; Penczek and Slomkowski, 1989a,b; Wodzki and Kaluzynski, 1989]. Other monomers that have been studied include cyclic phosphonites and phosphites as well as some sulfur analogs and nitrogen derivatives [Baran et al., 1989; Kobayashi et al., 1986]. 7-11e Sulfur and Sulfur Nitride Polymers

The stable form of sulfur under normal conditions is crystalline cyclooctasulfur, referred to as rhombic sulfur. Heating rhombic sulfur causes it to change into monoclinic sulfur (which is still cyclooctasulfur but with a different crystalline structure) at about 95 C. Further heating causes melting at about 119 C and ring-opening polymerization to catena-polysulfur at 150 180 C via a biradical propagating species [Laitinen et al., 1987; Meyer, 1976; Ray, 1978]. Catena polysulfur is elastomeric but is unstable it slowly reverts to rhombic sulfur on standing. Attempts to prevent this reversal by various means such as addition of small amounts of P, As, or alkenes (presumably to end-cap the polymer) have been unsuccessful. The polymerizations of selenium and tellurium proceed in a similar way as sulfur.

1 exp(-wTz)

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Some of the ways to address these vulnerabilities were to push patches and to ensure the antivirus definition files were up-to-date The problem was that people were working from home and most enterprises didn t have a means to push patches and update antivirus definitions for computer systems that weren t sitting on the LAN So users were using a vulnerable application, Internet Explorer, and surfing the Internet to all different kinds of sites Enterprises had no means of updating these systems That was a nightmare waiting to happen Enterprises can address the patching need by implementing a solution where their devices are patched any time they are connected to the Internet This necessitates a fundamental change in the patching topology The patching servers need to be accessible from the Internet.

7-119

Solid-state (topochemical) polymerization of cyclic disulfur dinitride to poly(sulfur nitride) (or polythiazyl), occurs on standing at ambient temperature or higher SN n , [Banister and Gorrell, 1998; Labes et al., 1979; Ray, 1978]. Disulfur dinitride is obtained by sublimation of tetrasulfur tetranitride. Polythiazyl is a potentially useful material, since it behaves like a metal. It has an electrical conductivity at room temperature about the same order of magnitude as a metal like mercury and is a superconductor at $0.3 C. Polythiazyl also has high light re ectivity and good thermal conductivity. However, it is insoluble and infusible, which prevents its practical utilization.

7-12

1 21 cosh(wTx)

Considerable work has been published on the copolymerizations of various cyclic monomers reacting through the same type of functional group (e.g., two cyclic ethers or two cyclic siloxanes) or through different types of functional groups (e.g., copolymerization of a cyclic ether with a lactone), and also the copolymerizations of cyclic monomers with alkenes and other compounds. Some copolymerizations of cyclic monomers are of commercial importance. These include the various cyclic ether and acetal copolymerizations described previously (Sec. 7-2b-7). Copolymerization is used extensively for silicone polymers. Varying amounts of substituents such as phenyl or vinyl are introduced into the basic poly(dimethylsiloxane) structure to modify properties of the nal product. Phenyl groups improve the lowtemperature exibility of silicone polymers by decreasing their low-temperature crystallinity. High-temperature performance and miscibility with organic solvents is also improved. Vinyl groups allow more ef cient crosslinking by either hydrosilation or peroxides. Although the literature contains much on copolymerizations of cyclic monomers, including data on monomer reactivity ratios, the reader is cautioned that most of the data are less reliable than corresponding data for radical copolymerizations of alkenes (Chap. 6). The

M n Mo X n 3-100

Some companies that recognize the need for this change and would like to implement it don t have the time, money, or resources to do so For these companies, the answer is to implement a managed patching solution The answer is not to be apathetic and do nothing to address the problem There are companies, such as Fiberlink, that offer managed Internet-based patching solutions for enterprises Figure 58 illustrates how LAN-based patching solutions are inadequate, while Figures 59 and 510 show different solutions to address the patching problem..

where Mo is the molecular weight of the monomer. The mode of termination is experimentally determined from the observation of the number of initiator fragments per polymer molecule. This requires the analysis of the molecular

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